Robinson group

A scanning electron microscope image of the side of a stack of nanosheets. The inset is an optical microscope image of a single exfoliated nanosheet, to show it is optically transparent.

Cornell materials scientists have developed an inexpensive, environmentally friendly way of synthesizing oxide crystal sheets, just nanometers thick, which have useful properties for electronics and alternative energy applications.

The work, led by Richard Robinson, assistant professor of materials science and engineering, is featured on the cover of the April 7 Journal of Materials Chemistry (Vol. 22, No. 13).

The millimeter-length, 20 nanometer-thick sodium-cobalt oxide crystals were derived through a novel method that combined a traditional sol-gel synthesis with an electric field-induced kinetic de-mixing step. It was this second step that led to the breakthrough of a bottom-up synthesis method through which tens of thousands of nanosheets self-assemble into a pellet.

The material has fascinating properties, Robinson said, including high thermoelectric power, high electrical conductivity, superconductivity and potential as a cathode material in sodium ion batteries.

Usually oxide materials, like a ceramic coffee mug, aren't electrically conductive; they're insulating, Robinson said. Since the material is a conductive oxide, it can be used in thermoelectric devices to convert waste heat into power. Now that the researchers have made nanosheets, they expect the material's thermoelectric efficiency to improve, enabling the creation of more efficient alternative energy thermoelectric devices.

The nanosheets also show the ability to bend, sometimes up to 180 degrees, Robinson added. This is unusual for ceramics, which are normally brittle.

The material is based on common, abundant elements (sodium, cobalt and oxygen), without toxic elements, such as tellurium, that are normally used in thermoelectric devices.

The paper's co-authors are graduate students Mahmut Aksit and David Toledo. The work was supported by the National Science Foundation and the U.S. Department of Energy, through the Energy Materials Center at Cornell (EMC2).